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Problem: Spontaneous Polarization

      The polarization of a molecule is described by the anharmonic equation of motion,

  equation2790

A linear chain of lattice spacing a is made of these molecules. The polarization is parallel to the chain, and each molecule is exposed to the electric field of the others. The temperature is zero, and quantum effects are negligible.

(a) For fixed values of the other parameters and tex2html_wrap_inline6835 the system develops a spontaneous polarization. What is the critical value of tex2html_wrap_inline5131 ?

(b) Calculate the magnitude of the static polarization tex2html_wrap_inline6839 as a function of tex2html_wrap_inline5131 . Show that, close to tex2html_wrap_inline6843 , tex2html_wrap_inline6845 , and calculate the exponent tex2html_wrap_inline5403 .      

 


This document can be accessed on the World Wide Web at "http//:solidstate.physics.sunysb.edu/book/prob/ ".

Laszlo Mihaly
Thu Oct 31 13:23:11 EST 1996


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