Atoms are arranged in a one-dimensional chain with a lattice spacing of a.
Each atom is represented by the potential
.
(a) Show that the electron energy E and wavenumber k satisfy the relationship
where
and
. Determine the
coefficient
.
(b) Calculate the energy gaps between the bands for weak potential,
and compare the result to the gaps obtained in the
nearly free-electron approximation.
(c) Calculate the bandwidth of the lowest-energy band for strong potential,
and compare the result to the bandwidth obtained in
the tight-binding approximation.
Laszlo Mihaly
Thu Oct 31 13:23:11 EST 1996