The volume dependence
of the phonon mode frequencies is approximated by
the Grüneisen relation,
, where
is a constant of the order of unity.
Calculate the pressure and the bulk modulus of the phonon gas.
Use the Debye approximation to
estimate the order of magnitude of this quantity and compare it to
the measured bulk moduli of solids.
Laszlo Mihaly
Thu Oct 31 13:23:11 EST 1996